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The book begins with a review of coating fundamentals, including the evolution of coating technology and the principles for coating formulation. Guidelines for coating design, selection, and application are presented. The structure of a coating system and the high-performance coating's essential properties and characteristics are covered in detail. Some standard testing methods for determining and evaluating coating properties are included.Coatings used in the oil/gas pipeline industry are then covered. Generally, pipeline coatings are divided into two categories (plant-applied and field-applied coatings). The authors describe primary coatings in both categories such as coal tar, asphalt, PE, liquid epoxy, FBE, and high-performance composite coating (HPCC), as well as field-applied liquid coatings (i.e., tape coatings, shrink sleeve, wax, mastics and many others) in terms of their structures, properties, products, and applications.Coating failures encountered on pipelines in the field are reviewed, including an analysis of its effect on pipeline integrity. Both permeable coatings and impermeable coatings receive particular attention, and their interactions with CP are discussed. The shielding effect of coating failures under a variety of scenarios is included to provide an understanding of this industry-important problem. The tests and results described in this chapter come from the authors' research activities. This first-hand information provides recommendations to the industry for avoiding incompatibility between pipeline coating candidates and CP.Stress corrosion cracking (SCC) has been a primary mechanism resulting in pipeline failure. It has been acknowledged that SCC occurrence is subject to coating failures. The authors focus on mechanistic aspects of the essential role of coating failures in pipeline SCC, including its initiation and propagation. Both near-neutral pH and high-pH SCC on pipelines are introduced, and correlations between the type and properties of coatings and their failure mechanisms are established. Discussions detail the development of solution chemistry and electrochemistry under disbonded coating to support SCC. Techniques for characterizing coating properties and testing coating performance in the field and research laboratory are also covered. The discussion provides insights essential to a complete testing and evaluation program for pipeline coating candidates, and for predicting long-term coating performance. Depending on an individual technique's capability and actual coating property needs, one can choose a testing method from convenient, simple inspection tools to complex, research-oriented equipment.Various coating application techniques are introduced and discussed, covering many important issues required for understanding what is necessary when a coating is applied to metal substrate, including pipelines. The content is based on realistic experiences.Finally, industrial experience with inspection and management of pipeline coatings is included. Inspections have been integral to the PIM (pipeline integrity management) program and ensure the integrity and safety of pipeline systems.
The world's population is steadily increasing and with it is an increasing demand for water-for both drinking and irrigation. In many areas of the world, particularly in warmer climates, there are limited sources from rivers and wells, so desalination is being increasingly used to produce water to satisfy both requirements. Although desalination is sometimes carried out on brackish waters and highly saline well waters, most desalination plants generate fresh water from seawater.There are three main processes used in desalination plants, the oldest of which is multistage flash (MSF), where the water is essentially boiled at low pressure and the steam that flashes off is condensed for drinking water.The second process is multiple-effect distillation (MED), in which low pressure steam is used to force evaporation of seawater and the vapor is then condensed for drinking water. Although actual MSF and MED plants(large-scale) are land based, small-scale units have been fitted to large ships, such as cruise liners, to generate fresh water.The third process is seawater reverse osmosis (SWRO), where chloride is selectively removed from water by forcing it at high pressure through a special membrane. This method involves no heat transfer but requires enough electricity to power the high-pressure pumps that are required. All three of these methods have advantages and disadvantages.This book looks at corrosion problems specific to MSF, MED, and SWRO osmosis desalination plants, describing their causes, some solutions, and the relative performance of various materials. It gives advice on procuring materials for desalination plants to avoid quality problems.
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