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An overview of the latest techniques for studying intermolecular interactions in crystalline matter.
This book will bring together world-leading experts, to describe the current state of play in the field and introduce the cutting-edge research and possible future directions into fluorescent chemosensors design.
We all learn - in schools, factories, bars and streets. We gather, store, process and transmit information in society. Molecular systems involved in our senses and within our brains allow all this to happen and molecular systems allow living things of all kinds to handle information for the purpose of survival and growth. Nevertheless, the vital link between molecules and computation was not generally appreciated until a few decades ago. Semiconductor-based information technology had penetrated society at many levels and the interest in maintaining momentum of this revolution led to the consideration of molecules, among others, as possible information handlers. Such an overlap between the recent engineering-oriented revolution with the ancient biology-oriented success story is very interesting and George Boole's times in Ireland 150 years ago produced the logic ideas that provide the foundations of computation to this day. Molecular logic and computation is a field which is 17 years young, has had a healthy growth and is a story which deserves to be told. It is a growing branch of chemical science which highlights the connection between information technology (engineering and biological) and chemistry. The author and co-workers of this publication launched molecular logic as an experimental field by publishing the first research in the primary literature in 1993 and are uniquely placed to recount how the field has grown. There is no other book at present on molecular logic and computation and is more comprehensive than that found in any review available so far. It shows how designed molecules can play the role of information processors in a wide variety of situations, once we are educated by those information processors already available in the semiconductor electronics business and in the natural world. Following a short history of the field, is a set of primers on logic, computing and photochemical principles which are an essential basis in this field. The book covers all of the Boolean logic gates driven by a single input and all of those with double inputs and the wide range of designs which lie beneath these gates is a particular highlight. The easily-available diversity of chemical systems is another highlight, especially when it leads to reconfigurable logic gates. Further on in the book, molecular arithmetic and other more complex logic operations, including those with a memory and those which stray beyond binary are covered. Then follows molecular computing approaches which lie outside the Boolean blueprint, including quantum phenomena and finally, the book catalogues the useful real-life applications of molecular logic and computation which are already available. This book is an authoritative, state of the art, reference and a 'one-stop-shop' concerning the current state of the field for scientists, academics and postgraduate students.
Porphyrin-based Supramolecular Architectures focuses on recent developments in the field, emphasising cutting-edge research and the diverse range of applications.
Supramolecular chemistry provides a versatile approach for modifying the structure and function of surfaces, including the formation of clusters, monolayers and films. This can be used in a variety of applications from porous surface systems, to modifiers of interface energy and sensor-based systems.Supramolecular Chemistry at Surfaces covers different methods of preparing and studying self-assembled structures at surfaces and interfaces. The book starts with a general introduction concerning the nature of surfaces followed by specific sections discussing different techniques to characterise surface-based supramolecular systems. Each chapter then goes on to address different surface systems including the surface of water; physisorbed layers at interfaces; chemisorbed layers at interfaces; polyelectrolyte systems; thin films; dynamic systems; and patterning.Written by a leading expert in the field, this is the first book to give a multidisciplinary view of the supramolecular aspects of interfaces providing the reader with an objective summary of all the deposition methods and their characterisation. The book will appeal to students and researchers in supramolecular chemistry, nanoscience, polymer chemistry and physics, surface science and materials science.
Polyrotaxane is a necklace-like supramolecule in which many cyclic molecules are threaded into a single polymer chain and can be cross-linked to produce functional polymeric materials. The resulting materials have movable cross-linking giving unique properties different from other polymer networks with fixed covalent bonds gaining much attention for new films, elastomers and coatings.Polyrotaxane and Slide-Ring Materials is the first book to cover the fundamentals and applications of these molecules and materials. After a general introduction, the first part of the book covers the thermodynamics of inclusion complex formation and sliding transition in polyrotaxane, followed by different synthesis techniques of polyrotaxane and slide-ring materials. The book then addresses different scattering methods for structural analysis followed by chapters on the electric and optical properties of polyrotaxane as well as the mechanical and thermodynamic properties of slide-ring materials. The final part of the book contains different chapters on their applications including gels elastomers and resins.Authored by the inventor of slide-ring materials, it will appeal to students, researchers, and engineers in supramolecular chemistry, polymer chemistry and polymer physics.
Porous materials with ultrahigh surface area are of great interest for potential applications in energy storage and environmental remediation. Porous Polymers describes the significant recent progress in the development of different porous frameworks, with a particular focus on the relationship between structure design, synthesis method and properties. The book starts with an introduction to porous materials and their functions followed by chapters looking at the design of porous polymers, synthesis methods of porous polymers (reversible methods, irreversible methods, copolymerization methods and self-polymerization methods); characterisation of porous polymer structures and post-synthesis techniques of porous polymers (lithiation, sulphonation, carbonization, grafting). Specific chapters then detail different porous materials systems such as conjugated microporous polymers (CMPs); covalent organic frameworks (COFs); hyper-crosslinked polymers (HCPs); polymers of intrinsic microporosity (PIMs); and porous aromatic frameworks (PAFs).Written by active researchers in the field, the book provides a comprehensive overview of different porous polymer systems for researchers and graduate students in chemistry and materials science working on novel materials and those interested in the energy and environmental applications.
This book is a must for advanced undergraduates and post-graduates studying bio-organic and supramolecular chemistry.
This book surveys highlights of the progress made in the creation of discrete synthetic assemblies and provides a foundation for new workers in the area.
This book addresses the exciting interface of supramolecular chemistry and protein science.
This book provides a complete overview of cucurbituril chemistry, covering fundamental aspects including history, synthesis and host-guest chemistry.
There have been great advances in biomedical imaging techniques in recent years and they are becoming prominent in supramolecular chemistry. This book will clarify the current understanding of these techniques.
This book combines co-crystal applications of commercial and practical interest from diverse fields into a single volume. It also examines effective structural design of co-crystals, and provides insights into practical synthesis and characterization techniques.
An authoritative resource covering the latest developments in different types of gels.
An overview of the latest advances in the synthesis, characterization and applications of dendrimers and other complex dendritic architectures.
A comprehensive overview of metallomacrocycles from designing complex functional metallosupramolecular systems to their applications.
This book provides a detailed and systematic overview of the history, development and current scientific knowledge and applications of supramolecular amphiphiles.
This book provides a comprehensive review of the structure and function of organic and metal-organic supramolecular materials, which will be of interest to students and researchers in this field.
This book provides a wide ranging survey of the latest findings and advances surrounding aromatic interactions, from the fundamentals to modern applications.
This book traces the origins of anion recognition as a unique sub-field in supramolecular chemistry, while illustrating the basic approaches used to effect receptor design.
This high level book is ideal for researchers both academic and industrial who require a comprehensive overview of the subject.
Leading experts provide a timely and comprehensive overview of the use of supramolecular systems in biomedical applications.
An accessible overview of the most effective synthetic receptors within the context of specific applications.
Essential reference material for postdoctoral researchers and postgraduate students providing background information on naphthalenediimide chemistry.
This book is an essential resource for anyone interested in the chemistry and applications of boron.
The only book to give a complete picture of current hydrogel research, covering all the major applications as well as the fundamental principles behind them.
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