Bøger i Topics in Organometallic Chemistry serien

In this book recent developments in dehydrogenation reactions catalyzed by 3d-metals are discussed. With continue efforts to develop sustainable chemical production the discovery of new catalysts and catalytic procedures for (de)hydrogenation reactions are a subject of great interest to the chemistry community. Additionally, (de)hydrogenation reactions enable the creation of closed-loop production cycles that support a circular economy. The chapters presented include the synthesis of heterocycles and tandem-multicomponent (three or more) reactions through dehydrogenative strategy, as well as the conversion of ethanol to n-butanol, higher oxidized hydrocarbons like acids, ester, amides from alcohols, ¿-alkylation of amines, ketones, and amides with alcohols and mechanistic understanding of dehydrogenation reactions with high-valent metals. With contributions from experts in the field, the book is a valuable resource for scholars working in the field of organometallic chemistry,catalysis, medicinal chemistry, as well as researchers in the industry.

This volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ¿SiH with carbon-carbon, carbon-heteroatom or heteroatom-heteroatom bonds and is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon molecular and macromolecular compounds. Yet these reactions do require a catalyst, for which initially homogeneous noble metal catalyst, mainly platinum, rhodium, iridium or ruthenium were used. However the high prices, metallic residues of these valuable catalysts as well as issues with product purification, did increase the interest in developing new catalysts. Noteworthy in this regard are the recently developed hydrosilylation reactions using catalysts based on earth-abundant transition metals (for example Mn, Fe, Co, Ni) and heterogeneous catalysts presented here. This volume of Topics in Organometallic Chemistry is written for scientists interested in silicon chemistry and its catalytic aspects, but can also be used as valuable handbook for postgraduate and advanced undergraduate students working with organometallic chemistry, catalysis as well as synthesis of fine chemicals.

This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.

This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient tools in synthesis and in industrial chemistry. It allows performing syntheses with short reaction times, atom economy, reduced consumption of energy and loss of reagents, and low level of wastes. Dinuclear complexes are known to be more efficient than the mononuclear analogues for the reaction rates and the selectivities. This book analyses the latest research, focusing on the key concepts, in building and using these dinuclear complexes. The book is aimed at researchers, graduate students and chemists at all levels in academia and industry.

This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field.

This book focuses on the computational modeling of organometallic reactivity. Given the broad interest and extensive application that computational methods have reached within the organometallic community, this new volume will attract the interest of both experimental and computational organometallic chemists.

This book focuses on the computational modeling of organometallic reactivity. Given the broad interest and extensive application that computational methods have reached within the organometallic community, this new volume will attract the interest of both experimental and computational organometallic chemists.

This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field.

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets.

This volume gives an overview of the applications of organometallic chemistry in process chemistry relevant to the current topics in synthetic chemistry. This volume starts with an introduction on the historical development of organometallics in process chemistry and is followed by chapters dealing with the last five years¿ development in various organometallic reaction types such as the challenging cross coupling process, construction of 3.1.0 bicycles, pressure and transfer hydrogenations of historically challenging compounds such as esters, utilization of carbon dioxide for making organic compounds by flow process, drug synthesis and metal detection and scavenging in the finished APIs. A chapter by Colacot et.al., is also devoted to the process development and structural understanding of organometallic catalysts with particular emphasis to LnPd(0) catalysts. An academia ¿ industry collaborated chapter on the use of water as a solvent for organometallic processes is included in this book.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

This volume presents a review of recent developments in nitrogen fixation using transition metal-dinitrogen complexes in the last decade. The authors are international experts in the corresponding field and each chapter discusses their latest achievements in the preparation of various transition metal-dinitrogen complexes and their reactivity.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

C-H bond oxidation using visible light leads mainly to the formation of C-O and C-N bonds, whereas cross-coupled C-C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.

In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. With the aim of complementing the well-established fields of homogeneous and enzymatic catalysis, organocatalysis and artificial metalloenzymes have enjoyed a recent revival.

This volume presents a review of recent developments in nitrogen fixation using transition metal-dinitrogen complexes in the last decade. The authors are international experts in the corresponding field and each chapter discusses their latest achievements in the preparation of various transition metal-dinitrogen complexes and their reactivity.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.